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Chemical SafetyI wanted to begin
this section with the precautionary steps when it comes to handling
chemicals. Before working with any chemicals, please keep in mind the
following:
-Keep any incompatible chemicals separate
-Inspect all containers for cracks or leaks
-Carry an MSDS sheet. An MSDS is a sheet containing all the data on a
product
including physical data, handling and working procedures, safe storage,
what to do
in case of a spill, levels of toxicity, how the chemical reacts with
other chemicals, and
safe disposal.
-Make sure all chemicals are strapped down and unable to move or spill
-Keep chemicals in a cool, dry area away from children
-Store chemicals in an area with good ventilation
-Take care to dispose of all chemicals properly
-Read all instructions carefully
-Use proper safety equipment such as gloves, facemask, respirator, and
clothing
cover
-Use different scoops and buckets for different chemicals to avoid
mixing them
-Do not stack containers. This can pose a hazard if one begins to leak
-Do not store or work with chemicals near an open flame
-Do not smoke near chemicals
-Do not mix chemicals.
-Do not add chemicals to the pool’s skimmer
-Chlorine fires need to be put out with water, not a chemical foam
extinguisher
Chlorine
Adding chlorine sanitizer to a pool creates free available chlorine,
which sanitizes the pool. Once the chlorine comes in contact with
harmful bacteria, it combines with the bacteria to kill it; it turns
into chloramine and won’t work to sanitize the pool. The free available
chlorine level should be between 1.0 and 4.0 parts per million. Too much
chlorine can cause breathing difficulties. When adding chlorine to a
pool, make sure to wear gloves and eye goggles. Never breathe in the
chlorine gas. Avoid skin contact with chlorine and never mix chlorine.
Liquid chlorine can be fed into the pool by a mechanical chlorinator or
added directly into the pool. Liquid chlorine is best used in large
pools because of its high pH level and should be used while the pool’s
filter is running. Chlorine gas is chlorine in its elemental state.
Chlorine gas is highly dangerous and very acidic, which is why it is not
used very often. The gas should be used with the utmost care to ensure
safety. Chlorine tablets use a more specialized form of chlorine because
the chlorine is pressed with cyanuric acid. Cyanuric acid acts as a
stabilizer that extends the life of the chlorine and makes the tablets
dissolve slowly. Tablets should only be placed in a floating feeder or
automatic chlorinator. Adding chlorine tablets to a skimmer can strip
the copper, and adding tablets to the pool can damage the plaster or
vinyl.
Chlorine tablets are also good at controlling the growth of algae.
Granular chlorine comes in three types: hypo-chlorites, Di-chlor, and
cal-hypo. Hypo-chlorites have less chlorine than other chlorine methods,
so more of the product is needed. To work effectively, hypo-chlorites
need to work in tandem with an acid. Hypo-chlorites are fast dissolving,
non-flammable, and won’t cause hard
water. Di-chlor is fast dissolving and also contains cyanuric acid, so
it lasts longer than the other types of granular chlorine. It is also
the most expensive.
Calcium hypochlorite
Calcium hypochlorite, or cal-hypo, comes in
tablets and granules. Cal-hypo is the least expensive, as well as the
most dangerous. Cal-hypo can catch fire if it comes into contact with
debris or other chemicals and must be used carefully. The calcium in
cal-hypo can cause hard water. Cal-hypo has a high pH value and must be
dissolved in a bucket of water before being added to a pool to avoid
bleaching the pool liner. When excess urine, saliva, fecal matter,
sunscreen, make up, or perspiration
combines with chlorinated water it can create chloramines, which can
cause skin and eye irritation. The level of chloramines should not
exceed 0.2 parts per million.
Bromine
Bromine is a chemical sanitizer but, unlike chlorine, bromine is less
irritating to the eyes and skin. Bromine levels for pools should be kept
above 1.0 parts per million. When bromine comes into contact with
bacteria, the bromine neutralizes the bacteria but remains active. Using
a shock treatment will kill off the harmful bacteria and leave the
working bromine behind. Thus, less bromine is needed in the long run.
Bromine most often comes in bromine tablets and bromine shock systems.
Bromine tablets contain a bromine residual that kills algae and
bacteria. Bromine is slow dissolving and is added to the pool with a
chemical feeder or dispenser. Bromine shock systems reactivate the
sanitizer in the bromine and eliminate the bromamines. Shock systems
work by drastically raising the chlorine or oxygen levels for a short
period of time.
Biguanide
Biguanide is an easier alternative to chlorine and bromine. Biguanide
doesn’t affect the pool’s pH levels and doesn’t have that chlorine
smell. Also, because of the nature of biguanide, all of the biguanide in
the water will act as a sanitizer all the time, even after killing off
bacteria. The biguanide itself does not work as an oxidizer, although
most biguanide products will come combined with an oxidizer. One
drawback of biguanide is that it has a tendency to gum up the pool’s
filter. Most pool supply stores will sell products to clean the gum from
the filter. Great care should be taken when using biguanide with other
chemicals. Biguanide should not be used with chlorine or select
monopersulfates. Check theproduct label for information on which
chemicals should and should not be used in tandem with
biguanide.Algaecide Algaecide is used to kill algae and prohibit algae
growth. It is important to use algaecide as some forms of algae are
resistant to chlorine. Once the algae has grown, it can be incredibly
hard to get rid of.There are four types of algaecides: quats, poly-quats,
colloidal silver, and copper salts. Quats are used mainly to prevent
algae from growing. Quats are the most available and the least
expensive. Poly-quats are mainly used to kill existing forms of algae.
While poly-quats are effective, they are also more expensive. Colloidal
silver sticks to pool walls, allowing the product to continue working
over time, and can reduce the need for chlorine. Colloidal silver should
be used carefully, as wrong doses can turn the pool walls black. Copper
salts are similar to colloidal silver. Copper salts both kill and
prevent algae, but should not be used in chlorinated pools.
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